UO(2)(2+)-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex

A new mixed hexaphyrin, pyrihexaphyrin (0.1.0.0.1.0) (1), was prepared via an acid catalyzed cyclization between 5,5′-(pyridine-2,6-diyl)bis(pyrrole-2-carbaldehyde) (2) and terpyrrole (3). This expanded porphyrin undergoes a ring contraction upon metallation with uranyl silylamide [UO(2)[N(SiMe(3))(...

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Detalles Bibliográficos
Autores principales: Brewster, James T., Root, Harrison D., Mangel, Daniel, Samia, Adam, Zafar, Hadiqa, Sedgwick, Adam C., Lynch, Vincent M., Sessler, Jonathan L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6552508/
https://www.ncbi.nlm.nih.gov/pubmed/31293744
http://dx.doi.org/10.1039/c9sc01593k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6552508/
https://www.ncbi.nlm.nih.gov/pubmed/31293744
http://dx.doi.org/10.1039/c9sc01593k

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