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A visible-light mediated three-component radical process using dithiocarbamate anion catalysis

We report a photoinduced three-component radical process, which couples readily available alkyl chlorides, maleimides, and heteroaromatic fragments to rapidly generate complex chiral products with high diastereocontrol. This method generates radicals via an S(N)2-based photochemical catalytic mechan...

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Detalles Bibliográficos
Autores principales: Cuadros, Sara, Horwitz, Matthew A., Schweitzer-Chaput, Bertrand, Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6553376/
https://www.ncbi.nlm.nih.gov/pubmed/31293731
http://dx.doi.org/10.1039/c9sc00833k