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Synthesis and Structures of Ruthenium Carbonyl Complexes Bearing Pyridine-Alkoxide Ligands and Their Catalytic Activity in Alcohol Oxidation

Reaction of Ru(3)(CO)(12) with two equiv of 6-bromopyridine alcohols 6-bromopyCHROH [(R = C(6)H(5) (L1); R = 4-CH(3)C(6)H(4) (L2); R = 4-OMeC(6)H(4) (L3); R = 4-ClC(6)H(4) (L4); (R = 4-CF(3)C(6)H(4) (L5); R = 2-OMeC(6)H(4) (L6); R = 2-CF(3)C(6)H(4) (L7)] and 6-bromopyC(Me)(2)OH (L8) in refluxing xyl...

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Detalles Bibliográficos
Autores principales: Yan, Xinlong, Yue, Xiaohui, Liu, Kang, Hao, Zhiqiang, Han, Zhangang, Lin, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6558070/
https://www.ncbi.nlm.nih.gov/pubmed/31214574
http://dx.doi.org/10.3389/fchem.2019.00394