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Improved Conditions for the Visible-Light Driven Hydrocarboxylation by Rh(I) and Photoredox Dual Catalysts Based on the Mechanistic Analyses

The improved catalytic conditions and detailed reaction mechanism of the visible-light driven hydrocarboxylation of alkenes with CO(2) by the Rh(I) and photoredox dual catalysts were investigated. The use of the benzimidazoline derivative, BI(OH)H, as a sacrificial electron donor was found to increa...

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Detalles Bibliográficos
Autores principales: Murata, Kei, Numasawa, Nobutsugu, Shimomaki, Katsuya, Takaya, Jun, Iwasawa, Nobuharu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6558419/
https://www.ncbi.nlm.nih.gov/pubmed/31231630
http://dx.doi.org/10.3389/fchem.2019.00371