Cargando…
Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role
Although the mechanism for the transformation of carbon dioxide to formate with copper hydride is well understood, it is not clear how formic acid is ultimately released. Herein, we show how formic acid is formed in the decomposition of the copper formate clusters Cu(II)(HCOO)(3) (−) and Cu(II)(2)(H...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6563433/ https://www.ncbi.nlm.nih.gov/pubmed/30958610 http://dx.doi.org/10.1002/cphc.201900095 |