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Activation and Photoinduced Release of Alkynes on a Biomimetic Tungsten Center: The Photochemical Behavior of the W−S‐Phoz System

The synthesis and structural determination of four tungsten alkyne complexes coordinated by the bio‐inspired S,N‐donor ligand 2‐(4′,4′‐dimethyloxazoline‐2′‐yl)thiophenolate (S‐Phoz) is presented. A previously established protocol that involved the reaction of the respective alkyne with the bis‐carbo...

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Detalles Bibliográficos
Autores principales: Peschel, Lydia M., Vidovič, Carina, Belaj, Ferdinand, Neshchadin, Dmytro, Mösch‐Zanetti, Nadia C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6563718/
https://www.ncbi.nlm.nih.gov/pubmed/30773712
http://dx.doi.org/10.1002/chem.201805665