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The effect of water on the validity of Löwenstein's rule

The common understanding of zeolite acidity is based on Löwenstein's rule, which states that Al–O–Al aluminium pairs are forbidden in zeolites. This rule is generally accepted to be inviolate in zeolites. However, recent computational research using a 0 K DFT model has suggested that the rule i...

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Detalles Bibliográficos
Autores principales: Heard, Christopher J., Grajciar, Lukáš, Nachtigall, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6563785/
https://www.ncbi.nlm.nih.gov/pubmed/31293755
http://dx.doi.org/10.1039/c9sc00725c