Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5

Treatment of MOF-5 with NbCl(4)(THF)(2) in acetonitrile leads to incorporation of Nb(iv) centers in a fashion that diverges from the established cation metathesis reactivity of this iconic material. A combination of X-ray absorption spectroscopy analysis and reactivity studies altogether supported b...

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Detalles Bibliográficos
Autores principales: Korzyński, Maciej D., Braglia, Luca, Borfecchia, Elisa, Lomachenko, Kirill A., Baldansuren, Amgalanbaatar, Hendon, Christopher H., Lamberti, Carlo, Dincă, Mircea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6566296/
https://www.ncbi.nlm.nih.gov/pubmed/31360395
http://dx.doi.org/10.1039/c9sc01553a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6566296/
https://www.ncbi.nlm.nih.gov/pubmed/31360395
http://dx.doi.org/10.1039/c9sc01553a

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