Stable radical versus reversible σ-bond formation of (porphyrinyl)dicyanomethyl radicals

(Porphyrinyl)dicyanomethyl radicals were produced by oxidation of dicyanomethyl-substituted porphyrins with PbO(2). These radicals constitute a rare example displaying stable radical versus dynamic covalent chemistry (DCC) depending upon the substitution position of the dicyanomethyl radical. meso-D...

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Detalles Bibliográficos
Autores principales: Adinarayana, B., Shimizu, Daiki, Furukawa, Ko, Osuka, Atsuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6566382/
https://www.ncbi.nlm.nih.gov/pubmed/31360409
http://dx.doi.org/10.1039/c9sc01631g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6566382/
https://www.ncbi.nlm.nih.gov/pubmed/31360409
http://dx.doi.org/10.1039/c9sc01631g

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