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An Unexpected Iron (II)-Based Homogeneous Catalytic System for Highly Efficient CO(2)-to-CO Conversion under Visible-Light Irradiation

We present two as-synthesized Fe(II)-based molecular catalysts with 1,10-phenanthroline (phen) ligands; Fe(phen)(3)Cl(2) (1) and [Fe(phen)(2)(CH(3)CH(2)OH)Cl]Cl (2), and their robust catalytic properties for the conversion of CO(2) to CO in DMF/TEOA (DMF = N,N’-dimethylformamide; TEOA = triethanolam...

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Detalles Bibliográficos
Autores principales: Fu, Zi-Cheng, Mi, Cheng, Sun, Yan, Yang, Zhi, Xu, Quan-Qing, Fu, Wen-Fu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6571623/
https://www.ncbi.nlm.nih.gov/pubmed/31100775
http://dx.doi.org/10.3390/molecules24101878