Unprecedentedly High Activity and/or High Regio-/Stereoselectivity of Fluorenyl-Based CGC Allyl-Type η(3):η(1)-tert-Butyl(dimethylfluorenylsilyl)amido Ligated Rare Earth Metal Monoalkyl Complexes in Olefin Polymerization

A series of fluorenyl-based constrained-geometry-configuration (CGC) allyl-type rare earth metal monoalkyl complexes bearing the divalent anionic η(3):η(1)-tert-butyl(dimethylfluorenylsilyl)amido (η(3):η(1)-FluSiMe(2)N(t)Bu) ligand (η(3):η(1)-FluSiMe(2)N(t)Bu)Ln(CH(2)SiMe(3))(THF)(2) (1–3) have been...

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Detalles Bibliográficos
Autores principales: Guo, Ge, Wu, Xiaolu, Yan, Xiangqian, Yan, Li, Li, Xiaofang, Zhang, Shaowen, Qiu, Nannan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572029/
https://www.ncbi.nlm.nih.gov/pubmed/31072012
http://dx.doi.org/10.3390/polym11050836

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572029/
https://www.ncbi.nlm.nih.gov/pubmed/31072012
http://dx.doi.org/10.3390/polym11050836

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