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Unprecedentedly High Activity and/or High Regio-/Stereoselectivity of Fluorenyl-Based CGC Allyl-Type η(3):η(1)-tert-Butyl(dimethylfluorenylsilyl)amido Ligated Rare Earth Metal Monoalkyl Complexes in Olefin Polymerization
A series of fluorenyl-based constrained-geometry-configuration (CGC) allyl-type rare earth metal monoalkyl complexes bearing the divalent anionic η(3):η(1)-tert-butyl(dimethylfluorenylsilyl)amido (η(3):η(1)-FluSiMe(2)N(t)Bu) ligand (η(3):η(1)-FluSiMe(2)N(t)Bu)Ln(CH(2)SiMe(3))(THF)(2) (1–3) have been...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572029/ https://www.ncbi.nlm.nih.gov/pubmed/31072012 http://dx.doi.org/10.3390/polym11050836 |