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Temperature-Controlled Assembly/Reassembly of Two Dicarboxylate-Based Three-Dimensional Co(II) Coordination Polymers with an Antiferromagnetic Metallic Layer and a Ferromagnetic Metallic Chain
Two new dicarboxylate-based three-dimensional cobalt coordination polymers, [Co(Me(2)mal)(bpe)(0.5)(H(2)O)](n) (1) and [Co(Me(2)mal)(bpe)(0.5)](n) (2), were synthesized from dimethylmalonic acid (H(2)-Me(2)mal) in temperature-controlled solvothermal reactions. Lower temperatures (60–80 °C) favored t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6572630/ https://www.ncbi.nlm.nih.gov/pubmed/31052601 http://dx.doi.org/10.3390/polym11050795 |