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Increase of Redox Potential during the Evolution of Enzymes Degrading Recalcitrant Lignin

To investigate how ligninolytic peroxidases acquired the uniquely high redox potential they show today, their ancestors were resurrected and characterized. Unfortunately, the transient Compounds I (CI) and II (CII) from peroxide activation of the enzyme resting state (RS) are unstable. Therefore, th...

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Detalles Bibliográficos
Autores principales: Ayuso‐Fernández, Iván, De Lacey, Antonio L., Cañada, Francisco J., Ruiz‐Dueñas, Francisco J., Martínez, Angel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582443/
https://www.ncbi.nlm.nih.gov/pubmed/30566756
http://dx.doi.org/10.1002/chem.201805679