Cargando…

[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential

Two novel κ(2)‐C,N‐pyridine bridged [FeFe]‐H(2)ase mimics (1 and 2) have been prepared and are shown to function as efficient molecular catalysts for electrocatalytic proton reduction. The elemental and structural composition of the complexes are confirmed by NMR and IR spectroscopy, high‐resolution...

Descripción completa

Detalles Bibliográficos
Autores principales: Schippers, Esther C. F., Nurttila, Sandra S., Oudsen, Jean‐Pierre H., Tromp, Moniek, Dzik, Wojciech I., van der Vlugt, Jarl Ivar, Reek, Joost N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582614/
https://www.ncbi.nlm.nih.gov/pubmed/31244551
http://dx.doi.org/10.1002/ejic.201900405