Cargando…
[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential
Two novel κ(2)‐C,N‐pyridine bridged [FeFe]‐H(2)ase mimics (1 and 2) have been prepared and are shown to function as efficient molecular catalysts for electrocatalytic proton reduction. The elemental and structural composition of the complexes are confirmed by NMR and IR spectroscopy, high‐resolution...
Autores principales: | Schippers, Esther C. F., Nurttila, Sandra S., Oudsen, Jean‐Pierre H., Tromp, Moniek, Dzik, Wojciech I., van der Vlugt, Jarl Ivar, Reek, Joost N. H. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6582614/ https://www.ncbi.nlm.nih.gov/pubmed/31244551 http://dx.doi.org/10.1002/ejic.201900405 |
Ejemplares similares
-
Photocatalytic Hydrogen Evolution by a Synthetic [FeFe] Hydrogenase Mimic Encapsulated in a Porphyrin Cage
por: Nurttila, Sandra S., et al.
Publicado: (2018) -
Photocatalytic Hydrogen Generation by Vesicle‐Embedded [FeFe]Hydrogenase Mimics: A Mechanistic Study
por: Becker, René, et al.
Publicado: (2019) -
Heteropolymetallic
[FeFe]-Hydrogenase Mimics: Synthesis
and Electrochemical Properties
por: Torres, Alejandro, et al.
Publicado: (2023) -
Serine is the molecular source of the NH(CH(2))(2) bridgehead moiety of the in vitro assembled [FeFe] hydrogenase H-cluster
por: Rao, Guodong, et al.
Publicado: (2019) -
Energetics for Proton Reduction in FeFe Hydrogenase
por: Siegbahn, Per E. M., et al.
Publicado: (2020)