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Revisiting a classical redox process on a gold electrode by operando ToF-SIMS: where does the gold go?

Electrochemical redox conversion between ferricyanide and ferrocyanide on a gold electrode is one of the most classical reactions in electrochemistry. In textbooks, the gold electrode is seen as chemically inert, on which only the adsorption/desorption of [Fe(CN)(6)](3/4–) and electron transfer take...

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Detalles Bibliográficos
Autores principales: Hua, Xin, Xia, Hai-Lun, Long, Yi-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6585599/
https://www.ncbi.nlm.nih.gov/pubmed/31360429
http://dx.doi.org/10.1039/c9sc00956f