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Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes

Pinacol boronic esters are highly valuable building blocks in organic synthesis. In contrast to the many protocols available on the functionalizing deboronation of alkyl boronic esters, protodeboronation is not well developed. Herein we report catalytic protodeboronation of 1°, 2° and 3° alkyl boron...

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Detalles Bibliográficos
Autores principales: Clausen, Florian, Kischkewitz, Marvin, Bergander, Klaus, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6585874/
https://www.ncbi.nlm.nih.gov/pubmed/31360428
http://dx.doi.org/10.1039/c9sc02067e