Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls

Catalytic asymmetric cycloadditions via transition-metal-containing dipolar intermediates are a powerful tool for synthesizing chiral heterocycles. However, within the field of palladium catalysis, compared with the well-developed normal electron-demand cycloadditions with electrophilic dipolarophil...

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Detalles Bibliográficos
Autores principales: Zhang, Mao-Mao, Wang, Ya-Ni, Wang, Bao-Cheng, Chen, Xiao-Wang, Lu, Liang-Qiu, Xiao, Wen-Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586609/
https://www.ncbi.nlm.nih.gov/pubmed/31221978
http://dx.doi.org/10.1038/s41467-019-10674-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586609/
https://www.ncbi.nlm.nih.gov/pubmed/31221978
http://dx.doi.org/10.1038/s41467-019-10674-3

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