Direct allylic C–H alkylation of enol silyl ethers enabled by photoredox–Brønsted base hybrid catalysis

Strategies for altering the reaction pathway of reactive intermediates are of significant importance in diversifying organic synthesis. Enol silyl ethers, versatile enolate equivalents, are known to undergo one-electron oxidation to generate the radical cations that spontaneously form electrophilic...

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Detalles Bibliográficos
Autores principales: Ohmatsu, Kohsuke, Nakashima, Tsubasa, Sato, Makoto, Ooi, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586846/
https://www.ncbi.nlm.nih.gov/pubmed/31221955
http://dx.doi.org/10.1038/s41467-019-10641-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6586846/
https://www.ncbi.nlm.nih.gov/pubmed/31221955
http://dx.doi.org/10.1038/s41467-019-10641-y

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