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Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition

[Image: see text] Ylide-substituted phosphines (YPhos) have been shown to be excellent ligands for several transition metal catalyzed reactions. Investigations of the coordination behavior of the YPhos ligand Y(S)PPh(2) (1) [with Y(S) = (Ph(3)P)(SO(2)Tol)C] toward group 9 and 10 metals revealed a su...

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Detalles Bibliográficos
Autores principales: Scherpf, Thorsten, Rodstein, Ilja, Paaßen, Maurice, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6588272/
https://www.ncbi.nlm.nih.gov/pubmed/31185547
http://dx.doi.org/10.1021/acs.inorgchem.9b00948