Cargando…
Group 9 and 10 Metal Complexes of an Ylide-Substituted Phosphine: Coordination versus Cyclometalation and Oxidative Addition
[Image: see text] Ylide-substituted phosphines (YPhos) have been shown to be excellent ligands for several transition metal catalyzed reactions. Investigations of the coordination behavior of the YPhos ligand Y(S)PPh(2) (1) [with Y(S) = (Ph(3)P)(SO(2)Tol)C] toward group 9 and 10 metals revealed a su...
Autores principales: | Scherpf, Thorsten, Rodstein, Ilja, Paaßen, Maurice, Gessner, Viktoria H. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2019
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6588272/ https://www.ncbi.nlm.nih.gov/pubmed/31185547 http://dx.doi.org/10.1021/acs.inorgchem.9b00948 |
Ejemplares similares
-
Unraveling the
High Activity of Ylide-Functionalized
Phosphines in Palladium-Catalyzed Amination Reactions: A Comparative
Study with (Cy)JohnPhos and PtBu(3)
por: Scharf, Lennart T., et al.
Publicado: (2019) -
Selective Pd-Catalyzed
Monoarylation of Small
Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized
Phosphines (YPhos)
por: Rodstein, Ilja, et al.
Publicado: (2020) -
Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone:
Angle Dependence of the Donor Strength
por: Löffler, Julian, et al.
Publicado: (2021) -
Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature
por: Tappen, Jens, et al.
Publicado: (2020) -
Ylide‐Functionalized Phosphines: Strong Donor Ligands for Homogeneous Catalysis
por: Scherpf, Thorsten, et al.
Publicado: (2018)