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Observation of Distinct Carboxylic Acid Conformers in Aqueous Solution

[Image: see text] We investigate the molecular geometry of the carboxyl group of formic acid in acetonitrile and aqueous solutions at room temperature with two-dimensional infrared spectroscopy (2D-IR). We found that the carboxyl group adopts two distinct configurations: a configuration in which the...

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Detalles Bibliográficos
Autores principales: Giubertoni, Giulia, Sofronov, Oleksandr O., Bakker, Huib J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6589744/
https://www.ncbi.nlm.nih.gov/pubmed/31125521
http://dx.doi.org/10.1021/acs.jpclett.9b00915