Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C−H Insertion, and Dimerization Reactions

Mesityl gold(I) carbenes lacking heteroatom stabilization or shielding ancillary ligands have been generated and spectroscopically characterized from chloro(mesityl)methylgold(I) carbenoids bearing JohnPhos‐type ligands by chloride abstraction with GaCl(3). The aryl carbenes react with PPh(3) and al...

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Detalles Bibliográficos
Autores principales: García‐Morales, Cristina, Pei, Xiao‐Li, Sarria Toro, Juan M., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593763/
https://www.ncbi.nlm.nih.gov/pubmed/30644625
http://dx.doi.org/10.1002/anie.201814577

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6593763/
https://www.ncbi.nlm.nih.gov/pubmed/30644625
http://dx.doi.org/10.1002/anie.201814577

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