A New Mode of Chemical Reactivity for Metal‐Free Hydrogen Activation by Lewis Acidic Boranes

We herein explore whether tris(aryl)borane Lewis acids are capable of cleaving H(2) outside of the usual Lewis acid/base chemistry described by the concept of frustrated Lewis pairs (FLPs). Instead of a Lewis base we use a chemical reductant to generate stable radical anions of two highly hindered b...

Descripción completa

Detalles Bibliográficos
Autores principales: Bennett, Elliot L., Lawrence, Elliot J., Blagg, Robin J., Mullen, Anna S., MacMillan, Fraser, Ehlers, Andreas W., Scott, Daniel J., Sapsford, Joshua S., Ashley, Andrew E., Wildgoose, Gregory G., Slootweg, J. Chris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6594078/
https://www.ncbi.nlm.nih.gov/pubmed/30968535
http://dx.doi.org/10.1002/anie.201900861

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6594078/
https://www.ncbi.nlm.nih.gov/pubmed/30968535
http://dx.doi.org/10.1002/anie.201900861

Ejemplares similares