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Acylation Reactions of Dibenzo‐7‐phosphanorbornadiene: DFT Mechanistic Insights
Extensive DFT calculations provide deep mechanistic insights into the acylation reactions of tert‐butyl dibenzo‐7‐phosphanobornadiene with PhCOX (X=Cl, Br, I, OTf) in CH(2)Cl(2) solution. Such reactions are initialized by the nucleophilic P⋅⋅⋅C attack to the carbonyl group to form the acylphosphoniu...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6594351/ https://www.ncbi.nlm.nih.gov/pubmed/31293872 http://dx.doi.org/10.1002/open.201900176 |