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Acylation Reactions of Dibenzo‐7‐phosphanorbornadiene: DFT Mechanistic Insights

Extensive DFT calculations provide deep mechanistic insights into the acylation reactions of tert‐butyl dibenzo‐7‐phosphanobornadiene with PhCOX (X=Cl, Br, I, OTf) in CH(2)Cl(2) solution. Such reactions are initialized by the nucleophilic P⋅⋅⋅C attack to the carbonyl group to form the acylphosphoniu...

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Detalles Bibliográficos
Autores principales:	Qu, Zheng‐Wang, Zhu, Hui, Grimme, Stefan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6594351/ https://www.ncbi.nlm.nih.gov/pubmed/31293872 http://dx.doi.org/10.1002/open.201900176

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