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Diiron oxo reactivity in a weak-field environment
Concomitant deprotonation and metalation of a dinucleating cofacial Pacman dipyrrin ligand platform (tBu)dmxH(2) with Fe(2)(Mes)(4) results in formation of a diiron complex ((tBu)dmx)Fe(2)(Mes)(2). Treatment of ((tBu)dmx)Fe(2)(Mes)(2) with one equivalent of water yields the diiron μ-oxo complex ((tB...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598509/ https://www.ncbi.nlm.nih.gov/pubmed/31341583 http://dx.doi.org/10.1039/c9sc00605b |