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Similarities and differences in d(6) low-spin ruthenium, rhodium and iridium half-sandwich complexes: synthesis, structure, cytotoxicity and interaction with biological targets
In this paper, we discussed the similarities and differences in d(6) low-spin half-sandwich ruthenium, rhodium and iridium complexes containing 2,2′-biimidazole (H(2)biim). Three new complexes, {[RuCl(H(2)biim)(η(6)-p-cymene)]PF(6)}(2)·H(2)O (1), [(η(5)-Cp)RhCl(H(2)biim)]PF(6) (2), and [(η(5)-Cp)IrC...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Berlin Heidelberg
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6598960/ https://www.ncbi.nlm.nih.gov/pubmed/31115765 http://dx.doi.org/10.1007/s00775-019-01665-2 |