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A novel synthetic strategy for styrene–butadiene–styrene tri-block copolymer with high cis-1,4 units via changing catalytic active centres
A styrene–butadiene–styrene tri-block copolymer (SBS) with a high cis-1,4 unit content (greater than 97%) was synthesized by a novel synthetic strategy based on changing the catalytic active centres using n-butyllithium and a nickel-based catalyst. Firstly, styrene was polymerized via anionic polyme...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6599772/ https://www.ncbi.nlm.nih.gov/pubmed/31312502 http://dx.doi.org/10.1098/rsos.190536 |