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Mechanistic and Kinetic Study on Self-/Cross- Condensation of PCTA/DT Formation Mechanisms from Three Types of Radicals of 2,4-Dichlorothiophenol

Chlorothiophenols (CTPs) are known to be key and direct precursors of polychlorinated thianthrene/dibenzothiophenes (PCTA/DTs). Self/cross-coupling of the chlorothiophenoxy radicals (CTPRs), sulfydryl-substituted phenyl radicals and thiophenoxyl diradicals evolving from CTPs are initial and importan...

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Detalles Bibliográficos
Autores principales: Wang, Hetong, Zuo, Chenpeng, Zheng, Siyuan, Sun, Yanhui, Xu, Fei, Zhang, Qingzhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600164/
https://www.ncbi.nlm.nih.gov/pubmed/31141990
http://dx.doi.org/10.3390/ijms20112623