Homo- and Copolymerization of Ethylene with Norbornene Catalyzed by Vanadium(III) Phosphine Complexes

Herein, we report the homo- and co-polymerization of ethylene (E) with norbornene (NB) catalyzed by vanadium(III) phosphine complexes of the type VCl(3)(PMe(n)Ph(3-n))(2) [n = 2 (1a), 1 (1b)] and VCl(3)(PR(3))(2) [R = phenyl (Ph, 1c), cyclohexyl (Cy, 1d), tert-butyl (tBu, 1e)]. In the presence of Et...

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Detalles Bibliográficos
Autores principales: Zanchin, Giorgia, Gavezzoli, Alessia, Bertini, Fabio, Ricci, Giovanni, Leone, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600629/
https://www.ncbi.nlm.nih.gov/pubmed/31159332
http://dx.doi.org/10.3390/molecules24112088

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6600629/
https://www.ncbi.nlm.nih.gov/pubmed/31159332
http://dx.doi.org/10.3390/molecules24112088

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