A reactive coordinatively saturated Mo(iii) complex: exploiting the hemi-lability of tris(tert-butoxy)silanolate ligands

Coordinatively unsaturated Mo(iii) complexes have been identified as highly reactive species able to activate dinitrogen without the need for a sacrificial reducing agent. Here, we report a coordinatively saturated octahedral Mo(iii) complex stabilized by κ(2)-tris(tert-butoxy)silanolate ligands, wh...

Descripción completa

Detalles Bibliográficos
Autores principales: Pucino, Margherita, Allouche, Florian, Gordon, Christopher P., Wӧrle, Michael, Mougel, Victor, Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6601292/
https://www.ncbi.nlm.nih.gov/pubmed/31341592
http://dx.doi.org/10.1039/c9sc01955c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6601292/
https://www.ncbi.nlm.nih.gov/pubmed/31341592
http://dx.doi.org/10.1039/c9sc01955c

Ejemplares similares