Synthesis of non-racemic 4-nitro-2-sulfonylbutan-1-ones via Ni(II)-catalyzed asymmetric Michael reaction of β-ketosulfones

Functionally substituted sulfones with stereogenic centers are valuable reagents in organic synthesis and key motifs in some bioactive compounds. The asymmetric Michael addition of β-ketosulfones to conjugated nitroalkenes in the presence of Ni(II) complexes with various chiral vicinal diamines was...

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Detalles Bibliográficos
Autores principales: Reznikov, Alexander N, Sibiryakova, Anastasiya E, Baimuratov, Marat R, Golovin, Eugene V, Rybakov, Victor B, Klimochkin, Yuri N
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604683/
https://www.ncbi.nlm.nih.gov/pubmed/31293677
http://dx.doi.org/10.3762/bjoc.15.127

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604683/
https://www.ncbi.nlm.nih.gov/pubmed/31293677
http://dx.doi.org/10.3762/bjoc.15.127

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