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Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantiosele...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604712/ https://www.ncbi.nlm.nih.gov/pubmed/31293679 http://dx.doi.org/10.3762/bjoc.15.129 |