Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantiosele...

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Detalles Bibliográficos
Autores principales: Zhang, Qichao, Lv, Jian, Luo, Sanzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604712/
https://www.ncbi.nlm.nih.gov/pubmed/31293679
http://dx.doi.org/10.3762/bjoc.15.129
Descripción
Sumario:The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels–Alder reaction of anthracene.

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