Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis

The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantiosele...

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Detalles Bibliográficos
Autores principales: Zhang, Qichao, Lv, Jian, Luo, Sanzhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604712/
https://www.ncbi.nlm.nih.gov/pubmed/31293679
http://dx.doi.org/10.3762/bjoc.15.129
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author Zhang, Qichao
Lv, Jian
Luo, Sanzhong
author_facet Zhang, Qichao
Lv, Jian
Luo, Sanzhong
author_sort Zhang, Qichao
collection PubMed
description The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels–Alder reaction of anthracene.
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spelling pubmed-66047122019-07-10 Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis Zhang, Qichao Lv, Jian Luo, Sanzhong Beilstein J Org Chem Full Research Paper The combination of the trityl cation and a chiral weakly coordinating Fe(III)-based bisphosphate anion was used to develop a new type of a highly active carbocation Lewis acid catalyst. The stereocontrol potential of the chiral tritylium ion pair was demonstrated by its application in an enantioselective Diels–Alder reaction of anthracene. Beilstein-Institut 2019-06-14 /pmc/articles/PMC6604712/ /pubmed/31293679 http://dx.doi.org/10.3762/bjoc.15.129 Text en Copyright © 2019, Zhang et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Zhang, Qichao
Lv, Jian
Luo, Sanzhong
Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title_full Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title_fullStr Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title_full_unstemmed Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title_short Enantioselective Diels–Alder reaction of anthracene by chiral tritylium catalysis
title_sort enantioselective diels–alder reaction of anthracene by chiral tritylium catalysis
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604712/
https://www.ncbi.nlm.nih.gov/pubmed/31293679
http://dx.doi.org/10.3762/bjoc.15.129
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AT lvjian enantioselectivedielsalderreactionofanthracenebychiraltrityliumcatalysis
AT luosanzhong enantioselectivedielsalderreactionofanthracenebychiraltrityliumcatalysis

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