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Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks

We report the synthesis of five dicarboxylic acid-substituted dipolar molecular rotors for the use as linker molecules in metal-organic frameworks (MOFs). The rotor molecules exhibit very low rotational barriers and decent to very high permanent, charge free dipole moments, as shown by density funct...

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Detalles Bibliográficos
Autores principales: Hamer, Sebastian, Röhricht, Fynn, Jakoby, Marius, Howard, Ian A, Zhang, Xianghui, Näther, Christian, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6604738/
https://www.ncbi.nlm.nih.gov/pubmed/31293682
http://dx.doi.org/10.3762/bjoc.15.132