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A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds
The facile synthesis of a rare two-coordinate acyclic silylene (R(2)Si:) that is stabilized using a bulky vinylic N-heterocyclic olefin ligand and the strongly σ-donating hypersilyl group [Si(SiMe(3))(3)](–) is reported. This vinyl-substituted silylene exhibits an excellent combination of prolonged...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6610552/ https://www.ncbi.nlm.nih.gov/pubmed/31341599 http://dx.doi.org/10.1039/c9sc01192g |