Site-selective C–H activation and regiospecific annulation using propargylic carbonates

Herein we describe an unprecedented Ru(II)-catalyzed site-selective and regiospecific annulation of benzoic acids with propargylic carbonates. The weakly coordinating carboxylic acid moiety outperformed other typically used directing groups in C–H activation, including ketone, nitrile, sulfonamide,...

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Detalles Bibliográficos
Autores principales: Lu, Qingquan, Mondal, Shobhan, Cembellín, Sara, Greßies, Steffen, Glorius, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6611066/
https://www.ncbi.nlm.nih.gov/pubmed/31341607
http://dx.doi.org/10.1039/c9sc01703h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6611066/
https://www.ncbi.nlm.nih.gov/pubmed/31341607
http://dx.doi.org/10.1039/c9sc01703h

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