The Zn(II)-1,4,7-Trimethyl-1,4,7-Triazacyclononane Complex: A Monometallic Catalyst Active in Two Protonation States

In this paper, the unusual reactivity of the complex Zn(II)-1,4,7-trimethyl-1, 4,7-triazacyclononane (2) in the transesterification of the RNA-model substrate, HPNP (3), is reported. The dependence of the reactivity (k(2)) with pH does not follow the characteristic bell-shape profile typical of comp...

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Detalles Bibliográficos
Autores principales: Diez-Castellnou, Marta, Salassa, Giovanni, Mancin, Fabrizio, Scrimin, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6616306/
https://www.ncbi.nlm.nih.gov/pubmed/31334218
http://dx.doi.org/10.3389/fchem.2019.00469

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6616306/
https://www.ncbi.nlm.nih.gov/pubmed/31334218
http://dx.doi.org/10.3389/fchem.2019.00469

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