M−O Bonding Beyond the Oxo Wall: Spectroscopy and Reactivity of Cobalt(III)‐Oxyl and Cobalt(III)‐Oxo Complexes

Terminal oxo complexes of late transition metals are frequently proposed reactive intermediates. However, they are scarcely known beyond Group 8. Using mass spectrometry, we prepared and characterized two such complexes: [(N4Py)Co(III)(O)](+) (1) and [(N4Py)Co(IV)(O)](2+) (2). Infrared photodissocia...

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Detalles Bibliográficos
Autores principales: Andris, Erik, Navrátil, Rafael, Jašík, Juraj, Srnec, Martin, Rodríguez, Mònica, Costas, Miquel, Roithová, Jana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6618258/
https://www.ncbi.nlm.nih.gov/pubmed/31083766
http://dx.doi.org/10.1002/anie.201904546

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6618258/
https://www.ncbi.nlm.nih.gov/pubmed/31083766
http://dx.doi.org/10.1002/anie.201904546

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