Selective C–F bond carboxylation of gem-difluoroalkenes with CO(2) by photoredox/palladium dual catalysis

The catalytic C–F bond carboxylation of organofluorines with CO(2) gas remains a challenging problem in synthetic chemistry. Here, we describe a selective defluorinative carboxylation of gem-difluoroalkenes through photoredox/palladium dual catalysis. The C–F bond activation is enabled by single ele...

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Detalles Bibliográficos
Autores principales: Zhu, Chuan, Zhang, Yu-Feng, Liu, Ze-Yao, Zhou, Lu, Liu, Haidong, Feng, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6625485/
https://www.ncbi.nlm.nih.gov/pubmed/31367327
http://dx.doi.org/10.1039/c9sc01336a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6625485/
https://www.ncbi.nlm.nih.gov/pubmed/31367327
http://dx.doi.org/10.1039/c9sc01336a

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