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Recyclable and Stable α-Methylproline-Derived Chiral Ligands for the Chemical Dynamic Kinetic Resolution of free C,N-Unprotected α-Amino Acids

A novel special designed, stable, and recyclable chiral ligand bearing a quaternary carbon was developed for chemical dynamic kinetic resolution (DKR) of free C,N-unprotected racemic α-amino acids via Schiff base intermediates. This method furnishes high yields with excellent enantioselectivity, has...

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Detalles Bibliográficos
Autores principales: Shu, Shuangjie, Zhao, Liang, Zhou, Shengbin, Wu, Chenglin, Liu, Hong, Wang, Jiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6630268/
https://www.ncbi.nlm.nih.gov/pubmed/31200582
http://dx.doi.org/10.3390/molecules24122218