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Superelectrophilic carbocations: preparation and reactions of a substrate with six ionizable groups

A substrate has been prepared having two triarylmethanol centers and four pyridine-type substituent groups. Upon ionization in the Brønsted superacid CF(3)SO(3)H, the substrate undergoes two types of reactions. In the presence of only the superacid, the highly ionized intermediate(s) provide a doubl...

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Detalles Bibliográficos
Autores principales: Kennedy, Sean H, Gasonoo, Makafui, Klumpp, Douglas A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6633208/
https://www.ncbi.nlm.nih.gov/pubmed/31354869
http://dx.doi.org/10.3762/bjoc.15.153