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Superelectrophilic carbocations: preparation and reactions of a substrate with six ionizable groups
A substrate has been prepared having two triarylmethanol centers and four pyridine-type substituent groups. Upon ionization in the Brønsted superacid CF(3)SO(3)H, the substrate undergoes two types of reactions. In the presence of only the superacid, the highly ionized intermediate(s) provide a doubl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6633208/ https://www.ncbi.nlm.nih.gov/pubmed/31354869 http://dx.doi.org/10.3762/bjoc.15.153 |