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Transient and intermediate carbocations in ruthenium tetroxide oxidation of saturated rings

The ruthenium tetroxide-mediated oxidation of cyclopentane, tetrahydrofuran, tetrahydrothiophene and N-substituted pyrrolidines has been studied computationally by DFT and topological (analysis of the electron localization function, ELF) methods. In agreement with experimental observations and previ...

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Detalles Bibliográficos
Autores principales: Pedrón, Manuel, Legnani, Laura, Chiacchio, Maria-Assunta, Caramella, Pierluigi, Tejero, Tomás, Merino, Pedro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6633598/
https://www.ncbi.nlm.nih.gov/pubmed/31354874
http://dx.doi.org/10.3762/bjoc.15.158