Cargando…
Cyclobutane dication, (CH(2))(4)(2+): a model for a two-electron four-center (2e-4c) Woodward–Hoffmann frozen transition state
The structures of the elusive cyclobutane dication, (CH(2))(4)(2+), were investigated at the MP2/cc-pVTZ and CCSD(T)/cc-pVTZ levels. Calculations show that the two-electron four-center (2e-4c) bonded structure 1 involving four carbon atoms is a minimum. The structure contains formally two tetracoord...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6633612/ https://www.ncbi.nlm.nih.gov/pubmed/31354864 http://dx.doi.org/10.3762/bjoc.15.148 |