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Cyclobutane dication, (CH(2))(4)(2+): a model for a two-electron four-center (2e-4c) Woodward–Hoffmann frozen transition state
The structures of the elusive cyclobutane dication, (CH(2))(4)(2+), were investigated at the MP2/cc-pVTZ and CCSD(T)/cc-pVTZ levels. Calculations show that the two-electron four-center (2e-4c) bonded structure 1 involving four carbon atoms is a minimum. The structure contains formally two tetracoord...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6633612/ https://www.ncbi.nlm.nih.gov/pubmed/31354864 http://dx.doi.org/10.3762/bjoc.15.148 |