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An Asymmetrically Substituted Aliphatic Bis-Dithiolene Mono-Oxido Molybdenum(IV) Complex With Ester and Alcohol Functions as Structural and Functional Active Site Model of Molybdoenzymes

A Mo(IV) mono-oxido bis-dithiolene complex, [MoO(mohdt)(2)](2−) (mohdt = 1-methoxy-1-oxo-4-hydroxy-but-2-ene-2,3-bis-thiolate) was synthesized as a structural and functional model for molybdenum oxidoreductase enzymes of the DMSO reductase family. It was comprehensively characterized by inter alia v...

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Detalles Bibliográficos
Autores principales: Ahmadi, Mohsen, Fischer, Christian, Ghosh, Ashta C., Schulzke, Carola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6637267/
https://www.ncbi.nlm.nih.gov/pubmed/31355183
http://dx.doi.org/10.3389/fchem.2019.00486