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Stabilization of Pancake Bonding in (TCNQ)(2) (.−) Dimers in the Radical‐Anionic Salt (N−CH(3)−2‐NH(2)−5Cl−Py)(TCNQ)(CH(3)CN) Solvate and Antiferromagnetism Induction

We report a new antiferromagnetic radical‐anion salt (RAS) formed from 7,7,8,8‐tetracyanquinonedimethane (TCNQ) anion and 2‐amino‐5‐chloro‐pyridine cation with the composition of (N−CH(3)−2‐NH(2)−5Cl−Py)(TCNQ)(CH(3)CN). The crystallographic data indicates the formation of (TCNQ)(2) (.−) radical‐anio...

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Detalles Bibliográficos
Autores principales: Starodub, Tetiana N., Čižmár, Erik, Kliuikov, Andrii, Starodub, Vladimir A., Feher, Alexander, Kozlowska, Mariana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6637699/
https://www.ncbi.nlm.nih.gov/pubmed/31360625
http://dx.doi.org/10.1002/open.201900179